Chemical resistant. 220 °C service. Inherently flame retardant.
Ryton PPS (polyphenylene sulfide) combines excellent chemical resistance, high-temperature service, and inherent flame retardancy (UL 94 V-0 without additives). Standard for automotive under-hood, pump components, electrical connectors, chemical processing where cost matters but performance is critical.
At a glance
- Density
- 1.66 g/cc
- Tensile strength
- 160 MPa
- Flexural modulus
- 14 GPa
- HDT (1.8 MPa)
- 260 °C
- Continuous service
- 220 °C
- Flame rating
- UL 94 V-0 (no additives)
- Chemical resistance
- Excellent (acids, bases, solvents)
- Water absorption
- < 0.02%
Key data
- Density
- 1.66 g/cc
- Tensile strength
- 160 MPa
- Flexural modulus
- 14 GPa
- HDT (1.8 MPa)
- 260 °C
- Continuous service
- 220 °C
- Flame rating
- UL 94 V-0 (no additives)
- Chemical resistance
- Excellent (acids, bases, solvents)
- Water absorption
- < 0.02%
PPS grades.
PPS R-4
Ryton R-4 from Solvay. 40% glass-filled. Standard grade — excellent mechanical properties. Used for structural and chemical applications.
PPS R-7
65% glass + mineral fillers. Highest stiffness and lowest creep. Used for demanding mechanical applications.
PPS Natural
Unfilled PPS. Easier machining, lower mechanical properties. Used for electrical insulators, chemical fittings.
PPS Conductive
Carbon-filled for ESD-dissipative applications. Electronics handling, RF components.
PPS High-Purity
Ultra-pure grade for semiconductor process equipment. Minimal ionic contamination.
PPS Low-Warp
Filler blend optimized for minimal dimensional change during processing. For precision applications.
PPS is typically filled for improved mechanical properties. Glass-filled is standard, with specialty filled versions for specific applications.
Why PPS for automotive.
220 °C continuous service
Handles under-hood temperatures including near-engine locations. Maintains properties indefinitely at elevated temperature.
Chemical resistance
Excellent resistance to automotive fluids — gasoline, diesel, coolant, oils, brake fluid, DEF. No swell, no degradation.
Inherently flame retardant
UL 94 V-0 without flame retardant additives. Better than FR-modified nylons — no additive migration over time.
Dimensional stability
Very low water absorption, low CTE, low creep. Parts maintain tolerances over life in humid/hot environments.
PPS has become the standard high-temperature plastic for under-hood automotive — beating nylon, PBT, and even PEI on balance of properties and cost.
PPS applications.
Automotive under-hood
Coolant pumps, thermostat housings, EGR components, turbo system parts
Fuel system components
Fuel pump housings, fuel rails, injector components
Electric motor components
EV motor stator components, insulators, connectors
Electrical connectors
High-temperature connectors requiring UL 94 V-0 rating
Pump housings
Chemical pump housings, industrial pump components
Semiconductor handling
Ultra-pure PPS for wafer handling, process equipment
Chemical processing
Chemical valve bodies, flow meters, processing equipment
LED headlight components
Structural components in LED headlights — temperature resistance
Industrial sensors
Sensor housings in high-temperature industrial environments
PPS finishing.
Injection molded
Primary process. PPS flows well, cycles fast. Standard for high-volume automotive.
Machined
PPS machinable with carbide tooling. Glass-filled grades wear tools faster — use PCD for production.
As-molded
Tan/beige color standard. Custom colors available.
Painted
Accepts paint with primer for adhesion.
Laser marked
Standard for identification.
Bonded
Can be ultrasonic welded to itself. Adhesive bonding requires surface preparation.
Threaded inserts
Heat-set or ultrasonic-installed brass inserts for threaded features.
Annealed
Post-processing annealing at 200 °C improves dimensional stability and reduces molded-in stress.
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Chemical resistant — questions
PPS vs PEEK — when is each right?
PPS: $15-25/kg for glass-filled, 220 °C service, very good chemistry. PEEK: $120-180/kg unfilled, 260 °C service, better chemistry, better mechanics, biocompatible grades. PEEK is 5-10× more expensive. For temperatures 180-220 °C, aggressive automotive chemistry, cost-sensitive production: PPS. For biomedical, continuous 220-260 °C, or max performance: PEEK.
Machining glass-filled PPS challenges?
Glass fiber content (typically 40%) is abrasive — tool life is 10-20% of unfilled PPS or nylon. Use polycrystalline diamond (PCD) tooling for production. Alternative: carbide tools with reduced feed rates. Dust contains glass fibers — use proper ventilation and PPE. Standard surface finish Ra 1.6-3.2 µm. For smoother surfaces, secondary polishing required.
Flame retardancy without additives — how?
PPS's molecular structure is inherently flame retardant — no additives needed. Aromatic sulfur-containing rings form a protective carbonaceous char when exposed to flame. Self-extinguishing. UL 94 V-0 rating achievable without red phosphorus, halogenated, or other FR additives. Advantage: no additive migration or leaching over time — consistent FR performance for decades.
Chemical compatibility?
PPS resists: most acids (sulfuric, hydrochloric, nitric dilute), bases, alcohols, aromatics, chlorinated solvents, automotive fluids, most petroleum products. Attacked by: concentrated oxidizing acids (conc. nitric, fuming sulfuric, chromic acid), molten alkalis. For most chemical service, PPS is excellent. For very aggressive oxidizers, PEEK or PTFE better.
Automotive EV applications?
PPS is the growing automotive plastic for EVs. Applications: electric motor stator end-winding covers, battery pack components, power electronics housings, cooling system components. EV systems have higher operating temperatures than conventional automotive, and PPS handles them. Also: EMI shielding requirements met with conductive PPS grades.
Cost-effective vs premium plastics?
PPS is the "sweet spot" high-temperature plastic. More expensive than commodity (nylon, PBT), much cheaper than premium (PEEK, PAI). For applications where nylon temperature limits are exceeded but full PEEK isn't needed, PPS is the right answer. Production economics at automotive volumes drive PPS adoption — injection molded PPS parts at $2-10 per part achievable.
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